Optimization time and mass of eggshell adsorbent in improving waste cooking oil quality
DOI:
10.29303/jpm.v17i5.3654Published:
2022-09-30Issue:
Vol. 17 No. 5 (2022): September 2022Keywords:
Acid Number, Eggshells, Cadmium, Waste Cooking OilArticles
Downloads
How to Cite
Downloads
Metrics
Abstract
Oxidation and hydrolysis damage to cooking oil can occur due to repeated use of cooking oil. Adsorption by utilizing eggshells, which contain high calcium carbonate and have a natural pore structure that can improve the quality of used cooking oil. This study aims to determine the physical properties and characteristics of the thermally activated chicken eggshell adsorbent and to determine the ability of the adsorbent to absorb acid and metal cadmium. The steps carried out in this study were the manufacture of adsorbents, quality tests of the adsorbents produced, and testing of adsorbents on used cooking oil samples based on acid numbers and decreasing levels of metal cadmium in the samples. The adsorption process of used cooking oil was carried out with variations in the mass of the adsorbent, namely 5, 7, 9, and 11 grams, and stirring time for 10, 20, 40, and 60 minutes. Based on the results of the study, it was found that the optimum conditions for decreasing the acid number with the use of an adsorbent mass of 11 grams and a stirring time of 60 minutes resulted in an acid number was 0.9974 mg NaOH/g with a decrease in the acid number of 76.54%, while for cadmium metal it decreased by 100% with adsorption capacity of 2.57124 mg/g.
References
Fitriyana, & Safitri, E. (2015). Pemanfaatan Cangkang Telur Ayam Sebagai Adsorben Untuk Meningkatkan Kualitas Minyak Jelantah. Konversi, 4,1 : 12–16.
Hidayati, P., Ulfin, I., & Juwono, H. (2016). Adsorpsi Zat Warna Remazol Brilliant Blue R Menggunakan Nata de coco: Optimasi Dosis Adsorben dan Waktu Kontak. Jurnal Sains Dan Seni ITS, 5, 2 : 134–136.
Tamrin. 2013. Gasifikasi Minyak Jelantah Pada Kompor Bertekanan [Waste Cooking Oil Gasification With Pressure Stoves]. Jurnal Teknik Pertanian Lampung, 2, 2 : 115–122.
Ketaren, S. 2012. Pengantar Teknologi Minyak dan Lemak Pangan. Jakarta: UI Press
Darmono. (1999). Kadmium (Cd) Dalam Lingkungan Dan Pengaruhnya Terhadap Kesehatan Dan Produkvitas Ternak. Wartazoa, 8, 1: 28 - 32.
Tizo, M. S., Blanco, L. A. V., Cagas, A. C. Q., Dela Cruz, B. R. B., Encoy, J. C., Gunting, J. V., Arazo, R. O., & Mabayo, V. I. F. (2018). Efficiency Of Calcium Carbonate From Eggshells As An Adsorbent For Cadmium Removal In Aqueous Solution. Sustainable Environment Research, 28, 6:326–332.
Pratiwi, S. W., Sari, S. N., Nurmalasari, R., & Indriani, M. (2020). Utilization of Nata De Coco as Adsorben in Methyl Orange Adsorption. EduChemia (Jurnal Kimia Dan Pendidikan), 5, 2: 187.
Haqiqi, E. R. (2018). Studi Awal Kemampuan Adsorpsi Komposit Kulit Telur Ayam dengan Sekam Padi sebagai Adsorben Metil Orange. CHEESA: Chemical Engineering Research Articles, 1, 1 : 15–20.
Pardede, E. (2020). Pemurnian Minyak Jelantah Menggunakan Adsorben Berbasis Cangkang Telur. Jurnal Atmosphere, 1, 1: 8–16.
Susanto, T. N., Atmono, A. A., & Natalina, N. N. (2017). Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Media Adsorben Dalam Penurunan Kadar Logam Kromium Heksavalen (Cr6+) Pada Limbah Cair Industri Elektroplating. Jurnal Ecolab, 11, 1: 27–31.
Mahhfudz, M. K., Utami, F. P., & Fitriyanto, S. (2018). Pemanfaatan Cangkang Telur Gallus Sp. Sebagai Adsorben Kadmium (Cd) Pada Limbah Cair Industri Batik. Dinamika Kerajinan Dan Batik: Majalah Ilmiah, 35, 2 :103.
Nurlaili, T., Kurniasari, L., & Ratnani, R. D. (2017). Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Adsorben Zat Warna Methyl Orange Dalam Larutan. Jurnal Inovasi Teknik Kimia, 2, 2 : 11–14.
Nadeak, S., Mentari Hasibuan, J., Widya Naibaho, L., & Suriani Sinaga, M. (2019). Pemanfaatan Limbah Cangkang Telur Ayam Sebagai Adsorben Pada Pemurnian Gliserol Dengan Metode Asidifikasi Dan Adsorpsi. Jurnal Teknik Kimia USU, 8 ,1 : 25–31.
Chraibi, S., Moussout, H., Boukhlifi, F., Ahlafi, H., & Alami, M. (2016). Utilization of Calcined Eggshell Waste as an Adsorbent for the Removal of Phenol from Aqueous Solution. Journal of Encapsulation and Adsorption Sciences, 6, 4:132–146.
Abatan, O.G., Alaba, P.A., Oni, B. A., Akpojevwe, K., Efeovbokhan, V., & Abnisa, F. 2020. Performance Of Eggshells Powder As An Adsorbent For Adsorption Of Hexavalent Chromium And Cadmium From Wastewater. SN Appl Sci. 2, 12:1-13.
Parvin, S., Mamun, A.-, Rubbi, M. F., Ruman, M. A., Rahman, M. M., & Biswas, B. K. (2020). Utilization Of Eggshell A Locally Available Biowaste Material, For Adsorptive Removal Of Congo Red From Aqueous Solution. Aceh International Journal of Science and Technology, 9, 2:63–74.
Kristanto, D., Pudjihastuti, I., & Amalia, R. (2021). The Effectiveness of Biosorbent from Chicken’s Egg Shell and Durian Peel towards the Quality of Biodiesel Product from Waste Cooking Oil. Journal of Vocational Studies on Applied Research, 3, 2:42–46.
Aini, Z., Yahdi, Y., & Sulistiyana, S. (2020). Kualitas Biodiesel Dari Minyak Jelantah Menggunakan Katalis Cangkang Telur Ayam Ras Dengan Perlakuan Suhu Yang Berbeda. Spin Jurnal Kimia & Pendidikan Kimia, 2, 2: 98–115.
Flores-Cano, J. V., Leyva-Ramos, R., Mendoza-Barron, J., Guerrero-Coronado, R. M., Aragón-Piña, A., & Labrada-Delgado, G. J. (2013). Sorption Mechanism Of Cd(II) From Water Solution Onto Chicken Eggshell. Applied Surface Science, 276, 682–690. https://doi.org/10.1016/J.APSUSC.2013.03.153
Ali, Z. T. A., Ibrahim, M. A., & Madhloom, H. M. (2016). Eggshell Powder As An Adsorbent for Removal of Cu (II) and Cd (II) from Aqueous Solution: Equilibrium, Kinetic and Thermodynamic Studies. Al-Nahrain University, College of Engineering Journal (NUCEJ), 19, 2:186–193.
Author Biography
Sani Widyastuti Pratiwi, Sekolah Tinggi Analis Bakti Asih Bandung
License
Copyright (c) 2022 Sani Widyastuti Pratiwi, Inggis Pinarti, Ratna Nurmalasari, Kenanga Triulfa Amadea, Srie Gustiani
This work is licensed under a Creative Commons Attribution 4.0 International License.
The following terms apply to authors who publish in this journal:
1. Authors retain copyright and grant the journal first publication rights, with the work simultaneously licensed under a Creative Commons Attribution License 4.0 International License (CC-BY License) that allows others to share the work with an acknowledgment of the work's authorship and first publication in this journal.
2. Authors may enter into separate, additional contractual arrangements for the non-exclusive distribution of the journal's published version of the work (e.g., posting it to an institutional repository or publishing it in a book), acknowledging its initial publication in this journal.
3. Before and during the submission process, authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website), as this can lead to productive exchanges as well as earlier and greater citation of published work (See The Effect of Open Access).