Kinetics study of copper (Cu) and chromium (Cr) adsorption using green mussel shells (Perna viridis) adsorbent

Authors

Febi Indah Fajarwati , Asfiya Mahanani , Mai Anugrahwati

DOI:

10.29303/jpm.v18i1.4613

Published:

2023-01-31

Issue:

Vol. 18 No. 1 (2023): January 2023

Keywords:

Green Shells, Adsorption, Copper (Cu), Chromium (Cr

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Fajarwati, F. I., Mahanani, A. ., & Anugrahwati, M. (2023). Kinetics study of copper (Cu) and chromium (Cr) adsorption using green mussel shells (Perna viridis) adsorbent. Jurnal Pijar Mipa, 18(1), 118–125. https://doi.org/10.29303/jpm.v18i1.4613

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Abstract

Research has been carried out on making green mussel shell adsorbents to absorb Cu and Cr metals. The study of making green mussel shell adsorbents was carried out by thermal activation using a furnace. The results of the activated adsorbent were characterized using FTIR and SEM-EDX. Furthermore, the adsorbent was used to absorb Cu and Cr metal by using several variations, namely variations in the temperature of the adsorbent activation, adsorbent weight, pH, and contact time, and knowing the kinetic model by determining the reaction order. The results obtained from the characterization of green mussel shells contain elements of Ca, about 67.56% at an activation temperature of 500 °C and 67.34% at an activation temperature of 900 °C. The optimum conditions for Cu metal adsorption by green shell adsorbent were obtained at an activation temperature of 500 °C, using an adsorbent of 1 gram under pH 10 and a contact time of 40 minutes. Whereas for Cr metal absorption, the activation temperature was 900 °C, the mass used was 1.5 grams with pH 7 and the contact time was 40 minutes. The adsorption kinetics model of green mussel shells adsorbent on Cu and Cr metals followed pseudo-second-order.

References

Zhang, W., Ou, J., Tang, M., He, Q., Long, A., Luo, S., ... & Wang, H. (2022). Physically-crosslinked activated CaCO3/polyaniline-polypyrrole-modified GO/alginate hydrogel sorbent with highly efficient removal of copper (II) from aqueous solution. Chemical Engineering Journal, 431, 133375.

Pratiwi, S. W., Gustiani, S., Amadea, K. T., Nurmalasari, R., & Pinarti, I. (2022). Optimization time and mass of eggshell adsorbent in improving waste cooking oil quality. Jurnal Pijar Mipa, 17(5), 683-690.

Agustina, T. E., Aprianti, T., & Miskah, S. (2017). Treatment of wastewater containing hexavalent chromium using zeolite ceramic adsorbent in adsorption column. International Journal on Advanced Science Engineering Information Technology, 7(2), 566-572.

DesMarias, T. L., & Costa, M. (2019). Mechanisms of chromium-induced toxicity. Current opinion in toxicology, 14, 1-7.

Sumarlan, I., & Alfarisa, S. (2018). Penentuan Nilai Ketidakpastian Analisis Merkuri (Hg) Pada Daun Singkong Menggunakan Metode Solid Sampling Atomic Absorption Spectrophotometry. Jurnal Pijar MIPA, 13(2), 147-150.

Zhang, M., Shen, H., Qian, Z., Liu, H., Tian, D., & Wang, X. (2022). Dual-purpose applications of magnetic phase-change microcapsules with crystalline-phase-tunable CaCO3 shell for waste heat recovery and heavy metal ion removal. Journal of Energy Storage, 55, 105672.

Jeffry Haryadi Nasution, I. (2015). Pembuatan Adsorben Dari Cangkang Kerang Bulu Yang Diaktivasi Secara Termal Sebagai Pengadsorpsi Fenol. Jurnal Teknik Kimia USU, 4(4).

Akhmad Anugerah S, I. (2015). Pemanfaatan Limbah Cangkang Kerang Bulu Sebagai Adsorben Untuk Menjerap Logam Kadmium (II) Dan Timbal (II). Jurnal Teknik Kimia USU, 4(3), 40-45.

Azizah, P., Ridlo, A., & Suryono, C. A. (2020). Mikroplastik pada Sedimen di Pantai Kartini Kabupaten Jepara Jawa Tengah. Journal of marine Research, 9(3), 326-332.

Al Rasyid, H., & Nasir, R. (2020). Kinetika Reaksi Transesterifikasi Minyak Biji Ketapang (Terminalia Catappa L) Pada Proses Produksi Metil Ester. Jurnal Pijar Mipa, 15(1), 77-87.

Rashidi, N. A., Mohamed, M., & Yusup, S. (2012). The kinetic model of calcination and carbonation of Anadara Granosa. International Journal of Renewable Energy Research, 2(3), 497-503.

Khan, A. A. A. (2016). Efektivitas Pemanfaatan Limbah Cangkang Kerang Dara (Anadara Granosa) Sebagai Media Adsorben Logam Cu (Ii) dalam (Doctoral dissertation, UII).

Yusop, M. F. M., Jaya, E. M. J., & Ahmad, M. A. (2022). Single-stage microwave assisted coconut shell based activated carbon for removal of Zn (II) ions from aqueous solution–Optimization and batch studies. Arabian Journal of Chemistry, 15(8), 104011.

Jiang, H., Srichuwong, S., Campbell, M., & Jane, J. L. (2010). Characterization of maize amylose-extender (ae) mutant starches. Part III: Structures and properties of the Naegeli dextrins. Carbohydrate polymers, 81(4), 885-891.

Adegoke, K. A., & Bello, O. S. (2015). Dye sequestration using agricultural wastes as adsorbents. Water resources and industry, 12, 8-24.

Widihati, I. A. G., Ratnayani, O., & Angelina, Y. (2010). Karakterisasi Keasaman dan Luas Permukaan Tempurung Kelapa Hijau (Cocos nucifera) dan Pemanfaatannya sebagai Biosorben Ion Cd2+. Jurnal Kimia, 4(1), 7-14.

Zaharia, M. M., Bucatariu, F., Doroftei, F., Loghin, D. F., Vasiliu, A. L., & Mihai, M. (2021). Multifunctional CaCO3/polyelectrolyte sorbents for heavy metal ions decontamination of synthetic waters. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 613, 126084.

Bernard, E., & Jimoh, A. (2013). Adsorption of Pb, Fe, Cu and Zn from industrial electroplating wastewater by orange peel activated carbon. International Journal of Engineering and Applied Sciences, 4(2), 95-103.

Nabiela, M., Hidayah, M., & Azizati, Z. (2020). Adsorpsi Ion Logam Kromium Heksavalen Cr (VI) Dalam Larutan Menggunakan Zeolit Berlapis Oksida Mangan (MnO2). Walisongo Journal of Chemistry, 3(2), 52-57.

Hastuti, S., & Mawahib, S. H. Setyoningsih. (2012). Penggunaan Serat Daun Nanas Sebagai Adsorben Zat Warna Procion Red Mx 8b. Jurnal Ekosains, 4(1), 41-47.

Husin, H., & Zaki, M. (2017). Adsorpsi Logam Cu (II) Menggunakan Kitosan dari Kulit Kerang Hijau. J-Innovation, 6(2), 9-16.

Hayuwardini, A., & Mulyani, B. (2022). Pemanfaatan arang ampas tebu (Bagasse) sebagai adsorben larutan campuran ion Pb2+ dan Cu2+. In Seminar Nasional Kimia dan Pendidikan Kimia (SN-KPK) (Vol. 13, No. 1, pp. 110-120).

Author Biographies

Febi Indah Fajarwati, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia

Asfiya Mahanani, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia

Mai Anugrahwati, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Islam Indonesia

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