Zeolite Synthesis Based Silica from Saccharum officinarum L. with Black Stem Using the Hydrothermal Method

Authors

Muhamad Redi , Intan Rizki Widya Astuti , Restu Agung Ramadhani , Baiq Nova Sopiana , Farhana Nida ul Adhya , Hidayatun Nikmah , Sudirman Sudirman , Baiq Nila Sari Ningsih

DOI:

10.29303/jpm.v19i3.6541

Published:

2024-05-19

Issue:

Vol. 19 No. 3 (2024): May 2024

Keywords:

Alumina; Saccharum officinarum L. with Black Stem; FTIR; Silica; Zeolite

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Redi, M., Astuti, I. R. W., Ramadhani, R. A., Sopiana, B. N., Adhya, F. N. ul, Nikmah, H., … Ningsih, B. N. S. (2024). Zeolite Synthesis Based Silica from Saccharum officinarum L. with Black Stem Using the Hydrothermal Method. Jurnal Pijar Mipa, 19(3), 473–478. https://doi.org/10.29303/jpm.v19i3.6541

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Abstract

Saccharum officinarum L. has a high amount of silica content, which can be used as the main component of zeolite synthesis. Silica was isolated from Saccharum officinarum L. bagasse with NaOH and HCl. This research aims to synthesize zeolite using silica from Saccharum officinarum L. with black stem and alumina from aluminium foil. The Saccharum officinarum L. used in this research was sourced from Lombok Island, West Nusa Tenggara Province, Indonesia. Silica was sourced from Saccharum officinarum L. using the sol-gel method. The silica from the isolation of dregs ash obtained 20 g of silica with a high percentage (yield) of 50%. This study found that 5.29 g of aluminium foil produced 14.29 g of alumina with the addition of 22.50 g of Na2CO3. The zeolite obtained was 3.88 g with a SiO2:Al2O3 ratio of 5:3. From this study, the percent (%) of obtained zeolite was 48.5% from the weight of the silica and alumina produced. The zeolite results synthesized from Saccharum officinarum L.  ash were characterized using FTIR. Based on the FTIR results, absorption was found at wave numbers (cm-1) 960, 729, and 668. The zeolite obtained was pure white and had a FTIR spectrum similar to that of Zeolite X from previous research. It can be predicted that the zeolite obtained from this research has been formed. This research is expected to be useful in increasing the effectiveness of the silica extraction process from Saccharum officinarum L. with black stem. Further analysis using XRD and SEM is needed to determine the characteristics of the zeolite produced.

References

Zhao, D., & Li, Y. R. (2015). Climate change and sugarcane production: potential impact and mitigation strategies. International Journal of Agronomy, 2015, 1-10.

Xu, Q., Ji, T., Gao, S. J., Yang, Z., & Wu, N. (2018). Characteristics and applications of sugar cane bagasse ash waste in cementitious materials. Materials, 12(1), 39.

Norsuraya, S., Fazlena, H., & Norhasyimi, R. (2016). Sugarcane bagasse as a renewable source of silica to synthesize Santa Barbara Amorphous-15 (SBA-15). Procedia Engineering, 148, 839-846.

Purnomo, C. W., Wirawan, S. K., & Hinode, H. (2019, June). The utilization of bagasse fly ash for mesoporous silica synthesis. IOP Conference Series: Materials Science and Engineering, 543(1), 012040.

Usman, A. M., Raji, A., Hassan, M. A., & Waziri, N. H. (2014). A comparative study on the properties of Al-7% Si-Rice husk ash and Al-7% Si-Bagasse ash composites produced by stir casting. The International Journal of Engineering and Science, 3(8), 1-7.

van Bokhoven, J. A., & Lamberti, C. (2014). Structure of aluminum, iron, and other heteroatoms in zeolites by X-ray absorption spectroscopy. Coordination Chemistry Reviews, 277, 275-290.

Ghulam, N. A., Abbas, M. N., & Sachit, D. E. (2019). Preparing of Alumina From Aluminium Waste. Int. J. Innov. Sci. Res. Technol, 4, 32019.

Becker, L. C., Boyer, I., Bergfeld, W. F., Belsito, D. V., Hill, R. A., Klaassen, C. D., Liebler, D. C., Marks Jr, J. G., Shank, R. C., Slaga, T. J., Snyder, P. W., & Andersen, F. A. (2016). Safety assessment of alumina and aluminum hydroxide as used in cosmetics. International journal of toxicology, 35(3), 16S-33S.

Jensen, Z., Kim, E., Kwon, S., Gani, T. Z., Román-Leshkov, Y., Moliner, M., Corma, A., & Olivetti, E. (2019). A machine learning approach to zeolite synthesis enabled by automatic literature data extraction. ACS central science, 5(5), 892-899.

Apriyani, N., & Novrianti, N. (2020). Penggunaan Karbon Aktif Dan Zeolit Tak Teraktivasi Dalam Alat Penyaring Air Limbah Laundry. Jukung (Jurnal Teknik Lingkungan), 6(1).

Abukhadra, M. R., & Mohamed, A. S. (2019). Adsorption removal of safranin dye contaminants from water using various types of natural zeolite. Silicon, 11, 1635-1647.

Kwakye-Awuah, B., Von-Kiti, E., Nkrumah, I., Erdoo Ikyreve, R., Radecka, I., & Williams, C. (2016). Parametric, equilibrium, and kinetic study of the removal of salt ions from Ghanaian seawater by adsorption onto zeolite X. Desalination and Water Treatment, 57(45), 21654-21663.

Li, H., Hui, J., Wang, C., Bao, W., & Sun, Z. (2014). Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method. Hydrometallurgy, 147, 183-187.

Tobarameekul, P., Sangsuradet, S., & Worathanakul, P. (2022). Comparative Study of Zn Loading on Advanced Functional Zeolite NaY from Bagasse Ash and Rice Husk Ash for Sustainable CO2 Adsorption with ANOVA and Factorial Design. Atmosphere, 13(2), 314.

Liu, C., Ma, H., & Gao, Y. (2019). Hydrothermal processing on potassic syenite powder: Zeolite synthesis and potassium release kinetics. Advanced Powder Technology, 30(11), 2483-2491.

Eddy, D. R., Noviyanti, A. R., & Janati, D. (2018). Sintesis Silika Metode Sol-Gel Sebagai Penyangga Fotokatalis Tio2 Terhadap Penurunan Kadar Kromium Dan Bes. Jurnal Sains Materi Indonesia, 17(2), 82.

Deviani, S. S., Mahatmanti, F. W., & Widiarti, N. (2018). Sintesis dan Karakterisasi Zeolit dari Abu Sekam Padi Menggunakan Metode Hidrotermal. Indonesian Journal of Chemical Science, 7(1), 86-93.

Muis, L., Sanova, A., & Suryadri, H. (2021). Karakterisasi zeolite dari ampas tebu yang dihasilkan dari reaktor hidrotermal dan aplikasinya pada penyerapan ion logam Pb2+. Chempublish Journal, 6(1), 1-11.

Yusuf, M., Suhendar, D., & Hadisantoso, E. P. (2014). Studi karakteristik silika gel hasil sintesis dari abu ampas tebu dengan variasi konsentrasi asam klorida. UIN SGD Bandung, 8(1), 159-181.

Rilyanti, M., Silviana, E. G., Buhani, B., Pandiangan, K. D., & Juliasih, N. L. G. R. (2020). Sintesis Dan Karakterisasi Zeolit Mordenit (Mor) Pori Hirarki Berbasis Silika Abu Ampas Tebu. Analit: Analytical and Environmental Chemistry, 5(2), 178-191.

Holmberg, B. A., Wang, H., Norbeck, J. M., & Yan, Y. (2003). Controlling size and yield of zeolite Y nanocrystals using tetramethylammonium bromide. Microporous and mesoporous materials, 59(1), 13-28.

Affandi, S., Setyawan, H., Winardi, S., Purwanto, A., & Balgis, R. (2009). A facile method for production of high-purity silica xerogels from bagasse ash. Advanced Powder Technology, 20(5), 468-472..

Sudirman, S., Munadi, M. Z., Dharmayani, N. K. T., Yuanita, E., Asnawati, D., Darmayanti, M. G., & Ulfa, M. (2022). Stationary phase performance based on calcium oxide/silica gel on thin-layer chromatography for xanthone derivative compounds. AIP Conference Proceedings, 2638(1), 020014.

Saravanan, S., & Dubey, R. S. (2020). Synthesis of SiO2 nanoparticles by sol-gel method and their optical and structural properties. Rom. J. Inf. Sci. Technol, 23(1), 105-112.

Arnelli, A., Afifah, N., Rizki, N., Windarti, T., & Astuti, Y. (2018). Synthesis of Zeolite from Sugar Cane as Detergent Builder: Variation of Si/Al Ratio and Hydrothermal TimeSynthesis of Zeolite from Sugar Cane as Detergent Builder: Variation of Si/Al Ratio and Hydrothermal Time. Jurnal Kimia Sains dan Aplikasi, 21(1), 24-28.

Ali, S., Amalia, S., & Fasya, A. G. (2015). Synthesis and Characterization of Zeolite Y From Bagasse Ash with Hydrothermal Temperatures Variations Using The Sol-Gel Method. ALCHEMY: Journal of Chemistry, 4(1), 88-92.

Boroglu, M. S., & Gurkaynak, M. A. (2011). Fabrication and characterization of silica modified polyimide–zeolite mixed matrix membranes for gas separation properties. Polymer Bulletin, 66, 463-478.

Ma, H., & Wu, C. (2023). Feasibility and performance evaluation of cementitious material mixed with coal gangue solid waste. In Managing Mining and Minerals Processing Wastes, 99-130.

Syaifie, P. H., Taufiq, A., & Wardhani, G. A. (2019). Sintesis, Karakterisasi dan Aplikasi Zeolit Berbahan Dasar Kaolin dan Abu Sekam Padi untuk Adsorpsi Logam Tembaga dan Krom dalam Limbah Cair Industri Pelapisan Logam. Jurnal Teknologi Bahan Dan Barang Teknik, 9(1), 17-24.

Author Biography

Muhamad Redi, University of Mataram

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Copyright (c) 2024 Muhamad Redi, Intan Rizki Widya Astuti, Restu Agung Ramadhani, Baiq Nova Sopiana, Farhana Nida ul Adhya, Hidayatun Nikmah, Sudirman Sudirman, Baiq Nila Sari Ningsih

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