Effect of Urea Variation Concentration on Slow Release Fertilizer (SRF) Based Chitosan/NaTPP/Calcium
DOI:
10.29303/jpm.v19i5.7401Published:
2024-09-30Issue:
Vol. 19 No. 5 (2024): September 2024Keywords:
Chitosan; Fertilizer; NaTPP; UreaArticles
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Abstract
Environmental pollution due to urea can negatively impact the environment and its surroundings. Efforts to prevent environmental pollution include encapsulating urea made of chitosan/NaTPP/Ca, which aims to determine its physical and chemical properties. This study crosslinks chitosan 1.66%, with NaTPP 3.33%, CaO, with variations in the addition of urea concentrations of 0.05%, 0.1%, 0.15%, 0.2%, and 0.25%. The results of FTIR characterization showed that there were functional groups OH-, C-H, Ca-O, NH, and P=O. The membrane weight yield ranges from 0.14-0.16 grams, while the average membrane thickness is 0.15-0.35 mm. The water absorption test is 1.86-2.64%, and the membrane porosity result is 0.91-2,25%. This shows that the membrane with a base material of 1.66% chitosan and 3.33% NaTPP is the best.
References
Amalia, D., & Fajri, R. (2020). Analisis Kadar Nitrogen dalam Pupuk Urea Prill dan Granule Menggunakan Metode Kjeldahl di PT Pupuk Iskandar Muda. Jurnal Kimia Sains dan Terapan.
Arafa, E. G., Sabaa, M. W., Mohamed, R. R., Elzanati, A. M., & Abdel-Gawad, O. F. (2022). Preparation of biodegradable sodium alginate/carboxymethylchitosan hydrogels for the slow-release of urea fertilizer and their antimicrobial activity. Reactive and Functional Polymers, 1-13.
Syifa, T., Isnaeni, S., & Rosmala, A. (2020). Pengaruh Jenis Pupuk Anorganik Terhadap Pertumbuhan dan Hasil Tanaman Sawi Pagoda (Brassicaee narinosa L.). Agroscript, 21-33.
Zafar, N., Niazi, M. B., Sher, F., Khalid, U., Jahan, Z., Shah, G. A., & Zia, M. (2021). Starch and polyvinyl alcohol encapsulated biodegradable nanocomposites for environment friendly slow release of urea fertilizer. Chemical Engineering Journal Advances, 1-12.
Rosjidi, M., Saputra, H., Wahyudi, I., Setyorini, D., & Widowat, L. R. (2018). Controlled Release Fertilizer (CRF) Used For Plant Of Red Onion . M.I.P.I., 191-196.
Putra, A. A., Karnata, I. N., & Winten, K. T. (2021). Pemberian Pupuk Urea Pada Tanaman Kangkung Darat (Ipomoea Reptans Poir) Dengan Jarak Tanam Yang Berbeda. Jurnal Ganec Swara, 1297-1305.
Lusiana, R. A., & Pranotoningtyas, W. P. (2018). Membran Kitosan Termodifikasi Tripolifosfat-Heparin Dan Aplikasinya Pada Permeasi Urea Dan Kreatinin. Analit: Analytical and Environmental Chemistry, 11-21.
Lusiana, R. A., Protoningtyas, W. P., Wijaya, A. R., Siswanta, D., Mudasir, & Santosa, S. J. (2017). Chitosan-Tripoly Phosphate (CS-TPP) Synthesis Through Cross-linking Process: The Effect of Concentration Towards Membrane Mechanical Characteristic and Urea Permeation. Oriental Journal Of Chemistry, 2913-2919.
Lusiana, R. A., & Pranotoningtyas, W. P. (2018). Analit: Analytical and Environmental Chemistry, 11-21.
Nasution, Z., Agusnar, H., Alfian, Z., & Wirjosentono, B. (2013). Pengaruh Viskositas Kitosan Dari Berbagai Berat Molekul Terhadap Pembuatan Kitosan Nanopartikel Menggunakan Ultrasonic Bath. Jurnal Teknologi Kimia Unimal, 68-79.
Ermina, P., Sumarheni, A. F., & Ismail, S. S. (2016). Formulasi Nanopartikel Ekstrak Bawang Dayak (Eleutherine Americana (Aubl) Merr) Dengan Variasi Konsentrasi Kitosan- Tripolifosfat (TPP). Journal of Tropical Pharmacy and Chemistry, 251-263.
Kencana, A. L. (2009). Perlakuan Sonikasi Terhadap Kitosan : Viskositas dan Bobot Molekul Kitosan. Institut Pertanian Bogor, Fakultas Matematika dan Ilmu Pengetahuan Alam, Skripsi.
Santo, M. C., Antoni, C. L., Rubio, A. P., & Alaimo, A. (2021). Chitosan-tripolyphosphate nanoparticles designed to encapsulate polyphenolic compounds for biomedical and pharmaceutical applications A review. Biomedicine & Pharmacotherapy, 1-24.
Nurratri, A. M., Khabib, Lusiana, R. A., Haris, A., & Nuryanto, R. (2020). Pembuatan Dan Karakterisasi Membran Paduan Kitosan Polietilenglikol6000. ISSN, 3261-3270.
Cahyaningrum, S. E., Lusiana, R. A., Natsir, T. A., Wardana, A. P., Purnamasari, A. P., & Misran, M. B. (2024). Synthesis and characterization of Chitosan Modified Membrane for Urea Slow Release Fertilizers. Heliyon, 1-17.
Rahayu, P., & Khabibi. (2016). Adsorpsi Ion Logam Nikel(II) oleh Kitosan Termodifikasi Tripolifosfat. Jurnal Kimia Sains dan Aplikasi, 21 – 26.
Abdillah, M., & Suprapto. (2022). Characterization and Modification of Corn Starch (Zea mays[L.]) and HPMC with Sodium Tripolyphosphate as Crosslinking Agent. Urecol Journal, 35-46.
Pinangsih, A. C., Wardhani, S., & Darjito. (2014). Sintesis Biokeramik Hidroksiapatit (Ca10(PO4)6(OH)2) dari Limbah Tulang Sapi Menggunakan Metode Sol-Gel. Kimia.Studentjournal, 203-209.
Saraswati, T. E., Sari, F. N., & Handayani, N. (2017). Karakter Permukaan Nanopartikel Besi Oksida/Karbon Tersintesis dalam Metode Submerged Arc Discharge menggunakan Media Larutan Etanol/Urea. Jurnal Penelitian Kimia,, 289-299.
Alauhdin, M., & Widiarti, N. (2014). Sintesis dan Modifikasi Lapis Tipis Kitosan Tripolifosfat. Jurnal MIPA, 46-52.
Tang, X., Yu, C., Lei, Y., Wang, Z., Wang, C., & Wang, J. (2022). A novel chitosan urea encapsulated material for persulfate slow-release to degrade organic pollutants. Journal of Hazardous Materials, 1-10.
Nurratri, A. M., Khabib, Lusiana, R. A., Haris, A., & Nuryanto, R. (2020). Pembuatan Dan Karakterisasi Polietilenglikol6000. ISSN, 3261-3270.
Rengga, W.D.P., Mubarok, M.A., Cahyarini, N.S. (2019). Phosphate release from Slow Release fertilizer using a mixture of Chitosan and potato Flour as a coating. Jurnal Bahan Alam Terbarukan, 34-40.
Trirahayu, D. A., Putra, R. P., Hidayat, A. S., Perdana, M. I., & Safitri, E. (2022). Synthesis and Performance Evaluation of Cellulose-based Slow-release Fertilizer: A Review. Jurnal Riset Kimia, 1-16.
Fatahu, Natsir, H., & Taba, P. (2015). Synthesis and Characterization of Chitosan Nanoparticles from the shells of crabs(Portunus pelagicus) and Application as Antimicrobial. Indonesia Chimica Acta, 17-28.
Suptijah, P. (2006). Deskripsi Karakteristik Fungsional dan Aplikasi Kitin Kitosan. Prosiding Seminar Nasional Kitin Kitosan , 14-24.
Thomas, M. S., Koshy, R. R., Mary, S. K., Thomas, S., & Pothan, L. A. (2019). Starch , Chitin and Chitosan Based Composites and Nanocomposites. Springer International Publishing.
D.R., B., & Pokharhar, V. (2006). Studies on Effect of pH on Crosslinking of Chitosan with Sodium Tripolyphosphate: A Thechnical Note. AAPS PharmSciTech, 50.
Khabibi, Suprihatin, & Hastuti, R. (2021). Modifikasi Kitosan Melalui Taut Silang Dengan Natrium Tripolifosfat Sebagai Adsorben Ion Mn(II). Media Bina Ilmiah, 5001-5008.
Haryono, Natanael, C. l., Rukiah, & Yuliati, Y. B. (2018). Kalsium Oksida Mikropartikel Dari Cangkang Telur Sebagai Katalis Pada Sintesis Biodiesel Dari Minyak Goreng Bekas. Jurnal Material dan Energi Indonesia , 8-14.
Author Biographies
Alvia Rachma Wijayanti, Department of Chemistry, Faculty of Mathematics and Natural Science, State University of Surabaya
Sari Edi Cahyaningrum, Department of Chemistry, Faculty of Mathematics and Natural Science, State University of Surabaya
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Copyright (c) 2024 Alvia Rachma Wijayanti, Sari Edi Cahyaningrum
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