Effect of concentration sulfuric acid on alumina extraction from napa soil
DOI:
10.29303/jpm.v18i5.5546Published:
2023-09-30Downloads
Abstract
West Sumatra is one of Indonesia's provinces with abundant and diverse natural potential. Based on data from the Department of Energy and Mineral Resources, West Sumatra province has a rich potential for metal and non-metallic minerals. Some types of minerals include gold lead (Au), zinc (Zn), manganese (Mn), coal, ironstone, and others. In iron ore, metal minerals contained iron minerals and gangue minerals such as silica and alumina. Napa soil is one of the materials found in West Sumatra containing aluminosilicate with a SiO2/ Al2O3 ratio of 63.20 %/ 16.55 %. It also contains TiO2, CaO, and K2O. Extraction of alumina generally using HCl or H2SO4 solvent. In previous research, HCl has been used as a solvent in extracting alumina from napa soil. Based on the literature search, no one has used H2SO4 as a solvent in the extraction of alumina from napa soil; therefore, it is necessary to conduct research as a material for further study. Therefore, this study will be conducted on variations in the concentration of acid solvents to determine the optimum amount of alumina products in the extraction of alumina in napa soil. In this study, the optimum results obtained alumina extraction with variations in the sulfuric acid concentration at a concentration of 6.0 M, with a % yield of 26.73%. The XRF analysis of alumina extraction showed that the Al2O3 content increased by 72.89%. Characterization of Alumina by FTIR indicated the presence of Al-O, Al-OH.
Keywords:
Napasoil, Alumina, Extraction, Sulfuric AcidReferences
Mishale Rieshapsari, A., Zainul Mafakhir, M., Muhammad Rieziq, N., Nail Adila, S., Anisa Putri, T., Sasongko, W., & Jalaluddin, M. (2020). Potensi Sumber Daya Mineral Logam Dan Non Logam Di Provinsi Sumatera Barat. 5(1).
Mishale Rieshapsari, A., Zainul Mafakhir, M., Muhammad Rieziq, N., Nail Adila, S., Anisa Putri, T., Sasongko, W., & Jalaluddin, M. (2020). Potensi Sumber Daya Mineral Logam Dan Non Logam Di Provinsi Sumatera Barat. 5(1).
Gangwar, J., Dey, K. K., Komal, Praveen, Tripathi, S. K., & Srivastava, A. K. (2011). Microstructure, phase formations and optical bands in nanostructured alumina. Advanced Materials Letters, 2(6), 402–408.
Fauzi, M., Mawardi, M., Kimia, J., Matematika, F., Ilmu, D., Alam, P., Negeri, U., Jln, P., Air, H., Padang, T., & 0751, I. T. (2019). PENGARUH VARIASI RASIO ALKALI AKTIVATOR TERHADAP HILANG PIJAR DAN KONSISTENSI NORMAL SEMEN GEOPOLIMER BERBASIS TANAH NAPA KABUPATEN LINTAU. Journal of RESIDU, 3.
Mawardi, M., Deyundha, D., Zainul, R., & Zalmi, P. R. (2018). Characterization of PCC Cement by Addition of Napa Soil from Subdistrict Sarilamak 50 Kota District as Alternative Additional Material for Semen Padang. IOP Conference Series: Materials Science and Engineering, 335(1).
Li, H., Hui, J., Wang, C., Bao, W., & Sun, Z. (2014). Extraction of alumina from coal fly ash by mixed-alkaline hydrothermal method. Hydrometallurgy, 147–148, 183–187.
ElDeeb, A. B., Brichkin, V. N., Kurtenkov, R. V., & Bormotov, I. S. (2019). Extraction of alumina from kaolin by a combination of pyro- and hydro-metallurgical processes. Applied Clay Science, 172, 146–154.
Tripathy, A. K., Behera, B., Aishvarya, V., Sheik, A. R., Dash, B., Sarangi, C. K., Tripathy, B. C., Sanjay, K., & Bhattacharya, I. N. (2019). Sodium fluoride assisted acid leaching of coal fly ash for the extraction of alumina. Minerals Engineering, 131, 140–145.
Cao, P., Luo, J., Jiang, H., Zhang, X., Rao, M., & Li, G. (2022). Extraction of alumina from low-grade kaolin in the presence of lime and NaOH via multi-stage hydrothermal process. Applied Clay Science, 229.
Shoppert, A. A., Loginova, I. V., Chaikin, L. I., & Rogozhnikov, D. A. (2017). Alkali Fusion-Leaching Method For Comprehensive Processing Of Fly Ash. KnE Materials Science, 2(2), 89.
Al-Zahrani, A. A., & Abdul-Majid, M. H. (2009). Extraction of Alumina from Local Clays by Hydrochloric Acid Process. In JKAU: Eng. Sci (Vol. 20, Issue 2).
Cui, L., Guo, Y., Wang, X., Du, Z., & Cheng, F. (2015). Dissolution kinetics of aluminum and iron from coal mining waste by hydrochloric acid. Chinese Journal of Chemical Engineering, 23(3), 590–596.
Fishherly, Arinda & Mawardi. (2022). Ekstraksi Alumina (Al2o3) Dari Mineral Tanah Napa Pesisir Selatan. Padang. Journal of Periodic, vol. 11, 2022.
Tantawy, M. A., & Ali Alomari, A. (2019). Extraction of Alumina from Nawan Kaolin by Acid Leaching. Oriental Journal of Chemistry, 35(3), 1013–1021.
Habashi, F. (2005). A short history of hydrometallurgy. Hydrometallurgy, 79(1–2), 15–22.
Patermarakis, G., & Paspaliaris, Y. (1989). The leaching of iron oxides in boehmitic bauxite by hydrochloric acid. Hydrometallurgy, 23(1), 77–90.
Guo, Y., Yan, K., Cui, L., Cheng, F., & Lou, H. H. (2014). Effect of Na2CO3 additive on the activation of coal gangue for alumina extraction. International Journal of Mineral Processing, 131(1), 51–57.
Bazin, C., El-Ouassiti, K., & Ouellet, V. (2007). Sequential leaching for the recovery of alumina from a Canadian clay. Hydrometallurgy, 88(1–4), 196–201.
Shandilya, M., Rai, R., & Singh, J. (2016). Review: Hydrothermal technology for smart materials. In Advances in Applied Ceramics (Vol. 115, Issue 6, pp. 354–376). Taylor and Francis Ltd.
Sunardi, S., Yateman Arryanto, Y., & Sutarno, S. (2010). ADSORPTION OF GIBBERELLIC ACID (GA3) ONTO ACID ACTIVATED KAOLIN. Indonesian Journal of Chemistry, 10(3), 320–326.
Ramli, Z., & Saleh, R. (2014). Preparation of Ordered Mesoporous Alumina Particles via Simple Precipitation Method. Malaysian Journal of Fundamental and Applied Sciences, 4(2)
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